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What do I need to do with Hazardous substances

Managing hazardous substances?

We are often asked what is required for managing hazardous substances. There are so many regulations, lots of numbers and letters. Here is a checklist for you.

Hazardous Substance Management Checklist

Inventory
Keep a current list of every hazardous substance and the maximum quantity likely to be on site, including hazardous waste. Make the inventory readily accessible to emergency service workers.
Safety Data Sheets (SDS)
Keep a current SDS, or the required condensed key information, for each hazardous substance. Make this information readily accessible to workers.
Labelling & signage
Ensure containers are correctly labelled wherever hazardous substances are used or stored. Display appropriate signage where required.
Safe storage & handling
Store and handle hazardous substances safely, using the containment, segregation and separation appropriate to their hazards.
Training & supervision
Ensure workers are trained and, where necessary, supervised to use and handle hazardous substances safely.
Emergency response
Have procedures in place for spills, fires, exposure and other emergencies, and ensure these align with your workplace emergency plan.

The classification and quantity determines what is required.

WorkSafe’s Hazardous Substances Calculator builds your inventory and tells you which controls apply — it is one way to find out exactly what you need to do. Unfortunately, it is not user friendly in that it does not use commercial names, does not deal well with “mixtures” and requires a HSNO number which not all SDS provide. Winsland’s comprehensive guide provides an alternative.

Hazardous Substance Quantity & Control Guide

The Health and Safety at Work (Hazardous Substances) Regulations 2017 apply different controls depending on the HSNO hazard classification and the quantity of the substance held or used at the workplace.

Important — classification:
The Regulations use HSNO hazard classifications, such as 3.1B, 6.1C and 8.2B. Current Safety Data Sheets generally use GHS classifications. Where necessary, establish the corresponding HSNO classification before applying the quantity thresholds in this guide.
Not sure about your classifications or quantities? Working out the HSNO classification and which quantity thresholds apply can be complicated. If you’re unsure what controls apply to your workplace, Winsland can help.

The tables below provide a practical summary of key quantity thresholds. They are not a substitute for checking the Regulations or the hazardous substances calculator, particularly where multiple substances are present.

1. Hazardous Substance Location / Location Compliance Certificate

A location compliance certificate may be required where specified flammable, oxidising, toxic or corrosive substances exceed the applicable quantity threshold.

HSNO classification Quantity threshold
2.1.1A / 2.1.1B 100 kg or 100 m³ permanent gas
2.1.2A 3,000 L aggregate water capacity
3.1A 20 L
3.1A — petrol, aviation gasoline, racing gasoline 50 L
3.1B 100 L in containers >5 L; 250 L in containers ≤5 L; 50 L open containers
3.1C 500 L in containers >5 L; 1,500 L in containers ≤5 L; 250 L open containers
3.2A–3.2C 1 L
4.1.1A 1 kg
4.1.1B 100 kg
4.1.2A–4.1.2B 1 kg
4.1.2C–4.1.2D 25 kg
4.1.2E–4.1.2G 50 kg
4.1.3A–4.1.3C 1 kg
4.2A 1 kg
4.2B–4.2C 25 kg
4.3A 1 kg
4.3B 25 kg
4.3C 50 kg
5.1.1A 50 kg or 50 L
5.1.1B 500 kg or 500 L
5.1.1C 1,000 kg or 1,000 L
5.1.2A 100 kg non-permanent gas or 200 m³ permanent gas
5.2A–5.2B 10 kg
5.2C–5.2D 25 kg
5.2E–5.2F 100 kg
6.1A 50 kg or 50 L
6.1B 250 kg or 250 L
6.1C 1,000 kg or 1,000 L
8.2A 50 kg or 50 L
8.2B 250 kg or 250 L

2. Fire Extinguishers

HSNO classification Quantity threshold Fire extinguishers
3.1A Over 50 L 1
3.1A Over 200 L 2
3.1B Over 250 L 2
3.1C–3.1D Over 500 L 2
4.1.2A–4.1.2G Over 50 kg or 50 L 1
4.1.2A–4.1.2G Over 200 kg or 200 L 2
4.2A Over 50 kg or 50 L 1
4.3A Over 50 kg or 50 L 1
5.1.1A Over 5 kg or 5 L 1
5.1.1A Over 25 kg or 25 L 2
5.2A–5.2B Over 1 kg or 1 L 1
5.2C–5.2D Over 10 kg or 10 L 1

3. Hazardous Substance Signage

HSNO classification Signage required above
3.1A 50 L
3.1B 250 L
3.1C 1,000 L
3.1D 10,000 L
5.1.1A 50 kg or 50 L
5.1.1B 500 kg or 500 L
6.1A 50 kg or 50 L
6.1B 250 kg or 250 L
6.1C 1,000 kg or 1,000 L
8.2A 50 kg or 50 L
8.2B 250 kg or 250 L

4. Emergency Response Plan & Secondary Containment

HSNO classification Threshold
3.1A 100 L
3.1B 1,000 L
3.1C–3.1D 10,000 L
4.1.2A–4.1.2B 50 kg or 50 L
4.1.2C–4.1.2D 100 kg or 100 L
4.2A 100 kg or 100 L
4.3A 100 kg or 100 L
5.1.1A 50 kg or 50 L
5.1.1B 500 kg or 500 L
5.1.1C 5,000 kg or 5,000 L
5.2A–5.2B 10 kg or 10 L
6.1A–6.1C 100 kg or 100 L
8.2A 100 kg or 100 L
8.2B 1,000 kg or 1,000 L
Important: The quantity thresholds in this guide are not necessarily applied to each substance in isolation. Some requirements depend on the combined quantities of substances present at the workplace and, in particular, the quantity-ratio sum (QRS). The actual requirements may also depend on the way substances are stored, their container sizes and whether substances are kept together or separated.

Need help working out what applies to your business?

Hazardous substance requirements can become complicated when different substances, classifications and quantities are involved. Winsland can help you identify your hazardous substances, establish the relevant classifications and determine what controls apply.

Contact Winsland →

Reference: Health and Safety at Work (Hazardous Substances) Regulations 2017, including the relevant schedules applying to hazardous substance classifications, quantities and workplace controls. This guide is a practical summary and should be checked against the current Regulations and WorkSafe guidance for specific situations.

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